Process for polymerizing conjugated dienes

ABSTRACT

CONJUGATED DIENES ARE POLYMERIZED BY A NEW CATALYST SYSTEM WHICH IS MORE ECONOMICALLY AND MORE EASILY PREPARED AND USED THAN PRESENT CATALYST SYSTEMS USED FOR SIMILAR PURPOSE. THIS CATALYST SYSTEM COMPRISES A COMBINATION OF A FREE RADICAL ANION COMPONENT MODIFIED BY POTASSIUM HYDROXIDE. THE FREE RADICAL ANIONIC COMPONENT IS MADE, IN AN APPROPRIATE SOLVENT, FROM AN ALKALI METAL AND AN ANION FORMING COMPOUND, SUCH AS NAPTHALENE. THE CATALYST SYSTEM IS USED TO POLYMERIZE CONJUGATED DIENES TO POLYMER PRODUCTS OF CONTROLLED MOLECULAR WEIGHT, SUITABLE FOR EASY PROCESSING AND HAVING PROPERTIES DESIRABLE FOR ULTIMATE USE IN TIRES AND OTHER MOLDED PRODUCTS. THE MOLECULAR WEIGHTS OF THE PRODUCTS ARE INCREASED BY VIRTUE OF THE MODIFIER AS COMPARED TO THE MOLECULAR WEIGHTS OBTAINED WITH THE RADICAL ANION COMPONENT ALONE.

, Patented Feb. 22, 1972 United States Patent Oflice ABSTRACT OF THE DISCLOSURE Conjugated dienes are polymerized by a new catalyst system which is more economically and more easily prepared and used than present catalyst systems used for similar purpose. This catalyst system comprises a combination of a free radical anion component modified by potassium hydroxide. The free radical anionic component is made, in an appropriate solvent, from an alkali metal and an anion forming compound, such as naphthalene. The catalyst system is used to polymerize conjugated dienes to polymer products of controlled molecular weight, suitable for easy processing and having properties desirablefor ultimate use in tires and other molded products. The molecular weights of the products are increased by virtue of the modifier as compared to the molecular Weights obtained with the radical anion component alone.

BACKGROUND OF THE INVENTION Field of the invention This invention relates to a process for the polymerization of dienes using a catalyst composition comprising an alkali metal free radical anionic compound associated with potassium hydroxide.

, Related prior art which are difficult to process for commercial use. This catalyst system generally comprises allyl sodium, sodium isopropoxide and sodium chloride. There are a number of literature references describing the Alfin process, typical' of which is the review article in Rubber Age, vol. 94, October 1963, pp. 87-92. The Alfin catalyst system effects very rapid formation of a very high molecular weight polymer having molecular weights of about 5,000,000 with about 75% of the polymer in the trans-1,4 configuration.

' Polymerization by an alkyl sodium, such as amyl sodium, produces a much slower polymerization reaction to give a polymer having as high as 70% in the 1,2- configuration with a molecular weight too low for desirable properties. Polybutadienes prepared by the use of n-butyl lithium in n-hexane have about 8-10% 1,2-; 53-54% trans-1,4; and 35%37% cis-1,4 configurations, which polymers do not have sufficient 1,2- configuration for the desired properties. By using polar modifiers or solvents,

such as ethers, amines, etc., the vinyl content can be in creased up to 50-70% However, the molecular weight distribution in such cases is so narrow as to give poor processability. More-v over, the polar modifiers act as chain terminators and prevent active polymer products that might be coupled or otherwise post-treated to improve the processability. Processability is very important for commercial rubber production. Among other disadvantages, poor processability results in poor adhesion to fillers and thereby gives poor reinforcement.

High glass transition temperatures in butadiene polymers generally indicate and accompany good wet traction. Butadiene emulsion polymers have low glass transition temperatures and have poor wet traction when fabricated into tires.

Alkali metal anionic catalysts, such as sodium naphthalenide, give low molecular weight polymers with poor processability.

In addition to the above disadvantages, most of the catalysts referred to above require very low temperatures, generally below 5 C. for preparation, and are more expensive to prepare since they require the reaction of an alkali metal, such as sodium, with a halogenated hydrocarbon, such as amyl chloride, butyl chloride, and the like, which results in the reaction of two atoms of sodium to prepare one mole of sodium alkyl, sodium allyl, etc.

British Pat. 965,259 discloses the use of a sodiumnaphthalene anion system used for the polymerization of styrene, butadiene and other monomers with the terminal anions of the product treated with chemical reagents to form terminal OH or COOH groups. The polymer products are low molecular weight and in most cases are liquid.

British Pat. 910,227 discloses the polymerization of dienes, preferably isoprene, to polymers resembling Hevea rubber and having or more, usually 93% or more, in the cis-1,4 addition structure. The catalyst system used is a lithium arylide or a polynuclear fused ring or contiguous ring aromatic hydrocarbon plus titanium trichloride. The solvents used in the polymerization are nonpolar, non-acidic organic solvents such as paraflins and cycloparaflins, including propane, pentane, cyclohexane, and the like. The resulting high cis-1,4 structure and consequently low 1,2- structure is not desirable from the standpoint of wet traction in tires molded from this product. For good wet traction it is desirable to have much higher proportions of 1,2- structure than obtained in the polymers made by the patentees process.

SUMMARY OF THE INVENTION In accordance with the present invention, it has now been found that conjugated diene polymers of controllable molecular weight, broad molecular weight distribution, good processability, high glass transition temperatures, and good wet traction are produced 'by the use of the catalyst system of this invention, which is less expensively and more easily and safely prepared than the catalyst systems mentioned above, and can be prepared and used at more convenient temperatures.

This catalyst system comprises a free radical alkali metal anionic derivative of an anion forming compound, such as naphthalene, diphenyl, anthracene, and the like, modified with potassium hydroxide. Advantageously the catalyst system is prepared and used in an appropriate solvent such as tetrahydrofuran, diglyme (the dimethyl ether of ethylene glycol), glyme-3 (the dimethyl ether of diethylene glycol), glyme-4 (the dimethyl ether of triethylene glycol), dimethyl ether, dioxane, methyl tetrahydrofuran, tetrahydropyran, acetonitrile, and the like including those listed in Radical Ions by Kaiser and Kevan, Chapters 2, 3 and 6,'published by John Wiley & Sons, Inc, New Yonk (1968). I

The anion components useful in the present invention may be broadly described as radical anion complexes of analkali metal with anion-forming compounds such as contiguous-ring aromatic hydrocarbons, tetramethylene ethaneand ketyls. Useful cyclic hydrocarbons include those having at least 10 carbon atoms, such as naphthalene, diphenyl, terphenyl, anthracene, phenanthrene, dihydrophenanthrene, triptycene, benzanthracene, naphthacene, chrysene, pyrene, perylene, coronene, dibenzanthracene, benzopyrene, cholanthrene, fluorene, tetramethylene ethane, and the like including those listed in Radical Ions by Kaiser and Kevan, Chapters 2, 3 and 6, published by John Wiley & Sons, Inc., New York (1968). Benzene, toluene, and the xylenes are not embodied in the groups of catalysts useful in the present invention. Most preferred is naphthalene. A less preferred group of compounds useful in forming catalysts with alkali metals are the ketyls, such as from benzophenone and xanthone.

The alkali metals useful in the complexes include lithium, sodium, potassium, rubidium and cesium. The preferred alkali metals are potassium, lithium and sodium.

The catalysts of this invention are prepared most conveniently by reacting substantially molar equivalents of the alkali metal and an anion forming compound of the aforementioned type preferably in an inert solvent for the complex and preferably a slight excess of the compound. While excess of either reagent may be present, the amount of anion formed will correspond to the stoichiometric amount for the reagent present in lower molecular amount.

The catalyst can be prepared at about room temperature and is advantageously aged overnight at about C. If not to be aged, the catalyst is advantageously pre pared at 5 C. In any case the temperature during preparation is advantageously no higher than about 30 C. Higher temperatures, particularly 60 C. or higher, produce side reactions which compete with the formation of the desired radical anions.

The ratio of catalyst components can be in the range of 0.5 to 4 moles of potassium hydroxide per mole of alkali metal anion, and preferably 1-3 moles per mole of anion.

The ratio of catalyst to monomer can be in the range of 0.1-1 millimole per 100 grams of monomer, preferably 0.2-0.5 millimole per 100 grams of monomer. This may be varied even more if low molecular weights can be tolerated. Moreover, the optimum amount may vary according to the polymerization temperature.

The solution concentrations are not critical but for obvious practical purposes it is preferably not to use too much sol-vent. The catalyst solution concentration is advantageously about 0.75 mole per liter.

The preferred solvents for the catalyst and the polymerization reaction medium are aliphatic and alycyclic ethers and the most preferred solvents are tetrahydrofuran, diglyme, dimethyl ether and the like as listed above. In addition to the ether solvent there may also be present inert hydrocarbon diluents such as butane, hexane, heptane, benzene and toluene in the preparation of the polymers of this invention.

, The polymerization reaction is conducted preferably in a closed reaction vessel and all operations are carried out in an inert atmosphere such as nitrogen. The reaction mixture is stirred rapidly during the course of the reaction and the catalyst is added to the monomer solution in the preferred procedure.

For best results the polymerization should be carried out at temperatures of from 5 C. to 100 C. and preferably from 30 C. to 50 C. With temperatures above 100 C. the molecular weight of the product decreases with increase in temperature, but where this can be tolerated temperatures as high as 200 C. can be used.

To prepare the radical anion the alkali metal is mixed or ground with fused-ring or contiguous-ring cyelic'hys drocarbon or other anion forming compound such as tetramethylene ethane, iketyls, and the like. The alkali metal and the cyclic hydrocarbon combine stoichiometrically, usually in the ratio of one" or two atoms of metal per mole of hydrocarbon, withoutth'e evolution of hydrogen or any other by-products. The product is salt-like in character; apparently an electron from the metal enters a cyclic pi orbital of the hydrocarbon, yielding a negatively charged hydrocarbon ion and a positively charged metal ion. As distinguished from the more familiar metal aryls, in which the metal such as sodium or lithium replaces a hydrogen atom of the aromatic hydrocarbon and is covalently bound to a carbon atom of the hydrocarbon, the metal arylides exhibit salt-like conductivity in the solid state, are relatively insoluble in hydrocarbon solvents, and reaction with mercury to form an amalgam and to regenerate the hydrocarbon. Hydrocarbons from which the arylides can be formed include the fused-ring aromatic hydrocarbons, and the contiguous-ring aromatic hydrocarbons, meaning by contiguous-ring aromatic hydrocarbons those in which a carbon of one ring is covalently bound to a carbon of another ring. Examples of such aromatic hydrocarbons include, for instance, naphthalene, anthracene, chrysene, biphenyl, fluorene, triphenylene, naphthacene, phenanthrene and the like. The general class of arylide compounds is discussed in an article by Paul et al. JACS 78, 116 (1956). For the most part, one gram-atom of metal combines with one mole of the hydrocarbon. However, in the case of biphenyl or triphenylene, two atoms of the metal may combine with each mole of hydrocarbon.

Diolefins suitable for use in this invention include butadiene, isoprene, 2-methyl-1,3-pentadiene, 2,3-dimethylbutadiene, cyclopentadiene, and the like. It will be understood that mixtures of diolefins may also be used.

The diolefins employed in this invention should be of a high degree of purity for use in the practice of this invention. It is desirable that the diolefin should be of at least mole percent purity and preferably in the neighborhood of or more mole percent purity. In general, the purer the diolefin, the faster the reaction rate. Acetylenic compounds, or other compounds containing reactive hydrogen which tend to reduce the effective catalyst concentration or to act as chain terminators should be kept at a minimum or removed prior to use, since they use up catalyst and also tend to lower the molecular weight of the resulting polymer. Any inhibitor normally present in a commercial diolefin must be removed by conventional techniques prior to polymerization in accordance with the invention.

For small scale laboratory preparations, the polymerization reactions may be conveniently carried out in glass bottles sealed by crown caps. These crown caps have several openings covered by an inner lining of rubber. Before use, the bottles should be dried, for instance 'by flaming with helium, argon, or other inert gas.

An atmosphere of inert gas such as helium, argon or the like is preferably maintained in the bottle during the charging to avoid contact of oxygen with the monomer, and it will usually be desirable to complete the purging of oxygen from the system by allowing a portion of the butadiene to evaporate with the bottle loosely capped, after which the crown cap is sealed. Then the composite catalyst, which will usually be in the form of a readily flowable solution of the catalyst, is introduced by means of a hypodermic syringe, the needle of which is inserted in one of the openings in the crown seal and pushed through the rubber liner. A hypodermic syringe is a convenient instrument for handling the catalyst, since it will keep the catalyst out of contact with the atmosphere. The sealed bottle may either be placed on a polymerizer wheel, arranged to dip and revolve the bottle in a water bath at the desired polymerization temperature, or after brief shaking or other agitation to mix the catalyst with the other ingredients, the bottle may be allowed to stand quiescent in ,a medium maintained at the desired polymerization temperature. a

The polymerization will usually be completed in from 3 to 60 hours, depending on the temperature, catalyst concentration and other pertinent conditions. It is usually necessary to cut open the bottle to remove the polymer. Since the polymer contains no antioxidants, it is extreme- 1y susceptible to oxidation. A preferred methodv of shielding the polymer from oxidation consists in dropping it into a methanol, isoropanol or other alcoholic solution of an antioxidant and agitating the mixture. The alcohol serves as a vehicle for distributing the antioxidant, as an agent to destroy the catalyst, and cause the polymer to separate out from the solvent used in the polymerization mass. The separated polymer is then preferably washed with water on a roll mill, usually with addition of further stabilizing agents, and dried.

Corresponding techniques should be used in large scale polymerizations. Usually the reaction will be carried out in a closed autoclave provided with a heat-transfer jacket and with a rotary agitator. Avoidance of oxygen contaminationis most easily secured by evacuating the vessel prior to charging the monomer and solvent and evaporating and venting a portion of the charge to sweep out any traces of oxygen present. As a precaution for the purity of the monomer and solvent, a silica gel or other suitable adsorption column is preferably inserted in the charging line for these materials. The catalyst is preferably charged last, conveniently from an auxiliary charging vessel pressured with an inert gas and communicating with the polymerization vessel'through a valved conduit. It is desirable to provide a reflux condenser to assist in the regulation of the reaction temperature which will usually be maintained between C. and 150 C., preferably between 30 and 80 C. Upon completion of the polymerization, the polymerization mass is removed, immersed under the surface of -a body of methanol, isopropanol or other alcohol containing an antioxidant, and agitated therewith to precipitate the polymer, destroy the catalyst and incorporate the antioxidant. The precipitated mass may be milled with water on a wash mill to remove the alcohol, additional antioxidant being incorporated during this operation. The product is then dried for storage and use.

Although butadiene homopolymers are preferred in the practice of this invention, other conjugated diene homopolymers and copolymers of the dienes can be used also where the comonomers impart desirable properties and do not detract from the polymer properties. The comonomers are preferably olefins, such as butene-l, nbutene-2, isobutylene, n-pentene-l, n-pentene-Z, and the "like, as well as other dienes, as listed above, and also including vinyl aryl or isopropenyl aryl compounds or derivatives thereof having alkyl, aralkyl, cycloalkyl or chlorine attached to the aromatic nucleus, and preferably having no more than 20 carbon atoms. Typical of these aromatic comonomers are styrene, alphamethyl styrene,

vinyl toluene, isopropenyl toluene, ethyl styrene, p-cyclohexyl styrene, 0-, mand p-Cl-styrene, vinyl naphthalene,

vinyl methyl naphthalene, vinyl butyl naphthalene, vinyl cyclohexyl naphthalene, isopropenyl naphthalene, isopropenyl isopropyl naphthalene, 1-vinyl-4-chloronaphthalene, 1-isopropenyl-S-chloro-naphthalene, vinyl diphenyl, vinyl diphenylethane, 4-vinyl-4'-methyl-diphenyl, 4 vinyl-4'- chlorodiphenyl, and the like. Preferably such comonomers have no more than 12 carbon atoms. Where such comonomers are to be used, generally at least 1%, preferably at least 5% by weight should be used and as much as 60%, preferably no more than 30% ma be used.

In referring herein to millimoles of catalyst this corresponds to the millimoles of anion complex since the catalyst is regarded or at least calculated as a complex of the metal alkoxide or aryloxide and the anion complex.

The polymerization is advantageously effected in the presence of an inert diluent to facilitate handling of the polymer and to give better temperature control. Normally liquid hydrocarbons are preferred for this purpose, such as benzene, toluene, saturated aliphatic hydrocarbons preferably of the straight chain variety, such as n-hex'ane, nheptane, etc. However, where provision is made foreX-' ternal heat dissipation and temperature'control, the solvent can be omitted.

The dilute solution viscosity referred to herein is defined as the inherent viscosityv determined at 25 .C. on a 0.4% solution of the polymer in toluene. It is calculated by dividing the natural logarithm of the relative viscosity by the percent concentration of the solution, i.e., it is the inherent viscosity measured at 0.4% concentration.

Polybutadienes having dilute solution viscosities in the range of 14, preferably 2-2.5 are found suitable to give the desired proper-ties for tire production and other molding purposes. Traslated to molecular weights DSVs correspond to polybutadiene molecular weights as follow: DSV of 1 means a mol. wt. of 60,000; DSV of 1.5 equals 100,- 000 mol. wt.; DSV of 2.6 equals 200,000 mol. wt.; DSV of 3.0 equals 240,000 mol. wt.; and DSV of 4.0 equals 320,000. Corresponding molecular weights of the other homopolymers and copolymers made according to this invention are also preferred for desired properties.

Various methods of practicing the invention are illustrated by the following examples. These examples are intended merely to illustrate the invention and not in any sense to limit the manner in which the invention can be practiced. The parts and percentages recited therein and all through the specification, unless specifically provided otherwise, are by Weight.

EXAMPLE I An anionic sodium naphthalenide-potassium hydroxide catalyst is prepared as follows. Naphthalene (21.5 g., 0.165 mole) is dissolved under a dry nitrogen atmosphere in 200 ml. of purified tetrahydrofuran and 3.45 g. (0.15 mole) of sodium is then added to it. After stirring 20 hrs. at 5 C., 16.8 g. (0.30 mole) of potassium hydroxide is added, after which stirring is continued for 3 hrs. at 5 C. Then the resultant mixture is stored at 10 C. until time for use.

EXAMPLE II Polymerization of butadiene is effected in a pressure reactor equipped with stirrer and heat-transfer jacket. A solution of 2410 g. containing 590 gms. of butadiene in hexane is charged into the reactor, which has previously been flushed with dry nitrogen. The monomer is then stirred for about 10 min. at 34 C. and 9 ml. (6.25 mmole) of the catalyst prepared in Example I is then added by means of a hypodermic syringe at 25 lbs. of nitrogen pressure at F. (27 C.). The system is immediately closed. After 6-8 hrs. stirring at 27 C., a polymer is obtained which is collected by pouring the mixture into a large amount of methanol containing 20 ml. of antioxidant agent. After drying, the polymer weight represents abou 99% yield.

EXAMPLE 111 An anionic sodium henanthracene-potassium hydroxide catalyst is prepared as follows. Phenanthracene (29.4 g., 0.165 mole) is dissolved in 200 ml. of tetrahydrofuran and 3.45 g. (0.15 mole) of sodium is then added to it. After stirring for 20 hours at 5 C., 8.4 g. (0.15 mole) of potassium hydroxide is added, after which stirring is continued at 5 C. for 3 hours. At the end of this time the reaction mixture is stored at 10 C. until time for use.

EXAMPLE IV Polymerization of butadiene is effected as follows: A solution of 260 g. containing 64 g. of butadiene in hexane is charged to a 28-02. moisture-free beverage bottle, which .7 has been flushed with dry nitrogen. 1.5 ml. (1.12 mmole) of .the catalyst prepared in Example III is then added with a, hypodermic syringe at 25 lbs. of nitrogen pressure. The bottle isi'mmediately immersed into a 30 C. constant temperature bath. After 6-8 hours stirring, the polymer is. collected by pouring the mixture into a large amount ofmethanol containing 2 ml. of antioxidant agent. After drying, the polymer weight represents about 98% theoretical yield.

EXAMPLE V An anionic lithium naphthalenide-potassium hydroxide catalyst is prepared as follows. Naphthalene (21.5 g., 0.165 mole) is dissolved in 200 ml. of purified tetrahydrofuran and 1.05 g. (0.15 mole) of lithium is then added to it. After stirring for 20 hrs. at 5 C., 8.4 g. (0.15 mole) of potassium hydroxide is added, after which stirring is continued at 5 C. for 3 hours. At the end of this time the reaction mixture is stored at C. until time for use.

EXAMPLE VI Polymerization of butadiene is effected with the catalyst of Example V as follows: A solution of 260 g. containing 64 g. of butadiene in hexane is charged into a 28-02. moisture-free beverage bottle, which has been flushed with dry nitrogen. 1.5 ml. (1.12 mmole) of catalyst is then added with a hypodermic syringe at lbs. of nitrogen pressure. The bottle is immediately immersed into a 30 C. constant temperature bath. After 6-8 hours stirring, the polymer is collected by pouring the mixture into a large amount of methanol containing 2 m1. of antioxidant agent. After drying, the polymer weight represents about 98% theoretical yield.

EXAMPLE VII The procedure of Examples I and II are repeated a number of times with similar results using equivalent amounts respectively of the following hydrocarbons in place of the naphthalene:

(a) Diphenyl (b) Dihydrophenanthrene (c) Pyrene (d) Benzopyrene (e) Fluorene (f) Tetramethylene ethane EXAMPLE VIII The procedures of Examples I and II are repeated at number of times with similar results using in place of the sodium equivalent amounts respectively of potassium, lithium, cesium and rubidium.

EXAMPLE IX The procedures of Examples II, IV and VI are repeated 21 number of times with similar results using in place of the butadiene equivalent amounts respectively of isoprene, piperylene, 2-methyl-1,3-pentadiene and cyclopentadiene.

EXAMPLE'X The procedures of Examples I and II are repeated at number of times with similar results using in place of the tetrahydrofuran equal amounts respectively of dimethyl ether of ethylene glycol (diglyme), dimethyl ether of diethylene glycol (glyme-3), dimethyl ether of triethylene glycol (g1yme-4), dioxane, methyltetrahyrofuran, tetrahydropyran, dimethyl ether and acetonitrile.

EXAMPLE XI The procedure of Example II is repeated a number of times with similar results using in place of the hexane an equal amount respectively of heptane, benzene, toluene and vcwclohexane.

EXAMPLE .xn

Comparative tests are made on a number of polybutadienes prepared according to Examples I and II containing 3742.7% 1,2- microstructure and controls of butyl lithium-catalyzed polybutadiene and styrene-butadiene rubbers of types being used commercially for tire produc tion. The polymers produced according to this invention show excellent resistance to cold flow. Moreover, the overall processability characteristics of these new polymers are better than the corresponding characteristics of the compared commercial types. When the respective polymers are blended respectively in a standard oil recipe and tested with standard laboratory traction devices, the new polymers of this invention when used 100% register wet traction improvement of about 15% above the controls. They also show very good wear properties.

The recipe used for the testing composition is 100 (parts) polymer; 70 ISAF black; 43 oil; 2.5 ZnO;2.0 stearic acid; 1.0 Santoflex 13; 1.7 sulfur; 1.4 Cyclex' B accelerator. This is cured for 30 minutes at 149 C. The results are tabulated in Tables I and v TABLE 1 Polybu'tadiene catalyzed with Na naphthalenide modified by K011 E F G 76 --76 -77 3. 83 4. 89 4. 50 Percent gel 0.0 0.0 0.0 Infrared analysis:

(Dis-1,4, percent 14. 3 14. 7 14. 8 Trans-1,4, percent" 50.3 48.3 49.2 1,2-, percer 1t 37.0 37.0 36.0 Williams plasticity at 22.8 0.:

3 min. reading, mm 8. 74 10. 20 10.12 1 mm. recovery, mm 2. 92 -3. 3. 30

TABLE II Evaluation of KHO-1nodified Na naphthalenide catalyzed polybutadlene Po1y- Controls 7 butadiene 2 mixture, I 1 II /III 1 E/F/G Ratio, percent 60 -10. 51 '35 14 ML/4/100 0. Compound 68 60 1 94 Mooney scorch at 0.:

T1--- 24.0 30.5 18.0 T10: 30. O i 36. U 27; 0 V, min 30.0 25; 0 45. 0 CEPAR rapid extrusion at Width/length, percent 70. 4 72. 6 68.2 Appearance Smooth Smooth Rough Garvey die extrusion test: i 1 .1

Extrusion temp, C 121 121 127 Extrusion rate, gins/mil 129. 0 111. 2 111. 5 Extrusion rating 16 16 v 2 11 730 710 I 720 640 590 470 600 520' 450 n propert I 4 days at 100 0.; cured 23 at 119 0.: r

300% modulus, p.s.i 1,950 2, 250 Tensile strength, p.s.i 2, 075 2,300 1, J50 Retention, percent .1 70 81 70 Ultimate elongation, percent 310 310 240 Retention, pereent 48 53 51 Ring tear at 100 0.; cure at C., lbs/in 349 341 254 Steel ball rebound cured 35 at 140 (1., percent:

At 218 (.1 r 38 35 44 At 100 C 51 61 00 See footnotes at end of table- TABLE IIContinued Poly- Controls butadiene 2 mixture, I 11 /Ill 1 E/F/G Shore A hardness, cured 25" at 149 C 58 59 61 Firestone flexometer Test-cured Shore A" hardness:

A1; 228 C 57 59 At temperature. 50 52 54 Deflection, percent 22. 7 22. 20. 0 Running temp., C. 135 135. 1i. Youngs bending modulus;

Cured 30 at 149 0., Index at 10,000 p.s.i., C -52 48 57 Stanley-London wet skid resistance; cured 30 at 149 0.-

Index at CF=0.40 95. 0 100.0 97. 8 Index at GF=0.57 95. 0 100. 0 101. 8

I is a commercial Styrene-Butadiene (18-72) Copolymer Rubber. 11 is a commercial Styrene-Butadiene (24-76) Copolymer Rubber. III is a commercial Lithium-Catalyzed Polybutadiene.

2 Polybutadienes identified as E, F, and G in Table 1.

EXAMPLE XIII The procedure of Example I is repeated to prepare suflicient catalyst for a number of polymerizations conducted with variations in the amount of catalyst and using the procedure of Example IV with the proportions of catalyst and various properties of the products as reported below in Table III. In each case the yield is about 100% of theoretical and no gel is formed. When these polymers are tested as tire compositions they show very good wear properties.

TABLE III I.R., percent Mmole cat./ ML/4l Recovery 0' Trans- 100 g. B.D. DSV 100 C. value T50. 1,4 1,4 1,2

While certain features of this invention have been described in detail with respect to various embodiments thereof, it will, of course, be apparent that other modifications can be made within the spirit and scope of this invention and it is not intended to limit the invention to the exact details shown above except insofar as they are defined in the following claims:

The invention claimed is:

1. A process of polymerizing at a temperature of 5100 C. a polymerizable monomer composition, in which the monomer portion comprises at least 70 percent by weight of a conjugated diene, which comprises polymerizing said composition in the presence of a catalyst consisting essentially of:

(a) a free radical anion component prepared by the reaction, in the presence of an inert solvent selected from the class consisting of acetonitrile and aliphatic and alicyclic ethers of substantially equivalent amounts, of an alkali metal with a compound selected from the class consisting of contiguous-ring aromatic hydrocarbons, tetramethylene ethane, benzophenone and xanthone, said contiguous-ring aromatic hydro- 10 carbons being selected from the class consisting of naphthalene, diphenyl, terphenyl, anthracene, phenanthrene, dihydrophenanthrene, triptycene, benzanthracene, naphthacene, chrysene, pyrene, perylene, coronene, dibenzanthracene, benzopyrene, cholanthrene and fiuorene; and

(b) potassium hydroxide; said anion component and said potassium hydroxide being used in the proportion of 0.5-4 moles of potassium hydroxide per mole of anion component, and said catalyst being used in a proportion of 0.1-1 millimoles of catalyst per parts by weight of polymerizable monomer.

2. The process of claim 1 in which said diene is butadiene.

3. The process of claim 1 in which said solvent is selected from the class consisting of tetrahydrofuran, dimethyl ether, dimethyl ether of ethylene glycol, dimethyl ether of diethylene glycol, dimethyl ether of triethylene glycol, dioxane, tetrahydropyran, methyl tetrahydrofuran and acetonitrile.

4. The process of claim 3 in which said solvent is tetrahydrofuran.

5. The process of claim 1 in which said polymerization temperature is 30'50 C.

6. The process of claim 1 in which said anion component is prepared at a temperature no higher than 30 C.

7. The process of claim 1 in which said catalyst composition has 1-3 moles of KOH per mole of alkali metal anion component.

8. The process of claim 1 in which said catalyst composition is used in a proportion of 0.20.S gram millimoles per 100 grams of monomer.

9. The process of claim 1 in which said anion component is a sodium compound.

10. The process of claim 1 in which said anion component is sodium naphthalenide.

11. The process of claim 1 in which said compound is phenanthrene.

12. The process of claim 1 in which said compound is anthracene.

13. The process of claim 1 in which said compound is tetramethylene ethane.

14. The process of claim 1 in which said monomer portion is substantially all butadiene.

15. The process of claim 1 in which said diene is isoprene.

16. The process of claim 1 in which said diene is 1,3- pentadiene.

17. The process of claim 1 in which said monomer portion also includes styrene.

References Cited UNITED STATES PATENTS 3,041,312 6/1962 Boyd 260-94.2 3,280,094 10/ 1966 Forman 260-942 3,326,881 6/1967 Uraneck et al. 2 60- 946 3,331,821 7/1967 Strobel 260-942 3,454,546 7/ 1969 Wilcoxen 26094.2

JAMES A. SEIDIJECK, Primary Examiner U.S. Cl. X.R.

P0405) UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3 9 +a3 Dated I Fe ruary 22, 972

Invehtor(s) F o B81838 It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown .below:

F- Col. 3, lin 53, "preferably" should read --pref-erable-- Col. 6, line 38, the after "follows" should be a line 6 ditto Col. 7, line 13, ditto 1 line 36, "procedure" should read -procedures-- Col. 8, line 4-2, "KHO" should read -KOH-- Signed and sealed this 25th day of Ju1' 1972.

(SEAL) Attest:

EDWARD M.FLETCHER,JR. ROBERT GOTTSCHALK Attesting Officer Commissioner of Patents 

